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* Department of Mineralogy, "Babes-Bolyai" University, Kogalniceanu 1, 3400 Cluj, and Speleological Institute "Emil Racovita", Clinicilor 5, 3400 Cluj, Romania
** George Veni Associates, 11304 Candle Park, San Antonio, TX 78249, USA
*** Department of Geosciences and Materials Research Laboratory, The Pennsylvania State University, University Park, PA 16802, USA.
e-mail: wbw2{at}psu.edu
A new mineral association composed of metatyuyamunite, celestite, opal and several minor crystalline phases has been identified in the Caverns of Sonora (Texas). The minerals were identified by means of X-ray diffractometry and optical and scanning electron microscopy. The main component of this association is metatyuyamunite, a uranyl vanadate mineral that appears as aggregates of sub-millimeter platy-like crystals that are often covered by botryoidal opal coatings. The orthorhombic unit cell of the Sonora metatyuyamunite had parameters a = 10.418, b = 8.508, and c = 17.173 Å. Opal and celestite formed either directly over the yellow crust or along the cracks that traverse the limy mud on which metatyuyamunite was precipitated. The secondary uranium-vanadium minerals described herein were precipitated in the final stages of cave development.
Key-words: metatyuyamunite, celestite, cave mineralogy, Sonora (Texas).
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