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European Journal of Mineralogy; September, October 2001; v. 13; no. 5; p. 857-861; DOI: 10.1127/0935-1221/2001/0013-0857
© 2001 E. Schweizerbart'sche Verlagsbuchhandlung Science Publishers
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Articles

Stability of (Mg0.5Fe0.5)O and (Mg0.8Fe0.2)O magnesiowüstites in the lower mantle

Leonid DUBROVINSKY*, Natalia DUBROVINSKAIA, Hans ANNERSTEN, Elke HÅLENIUS and Hans HARRYSON

Institute of Earth Sciences, Uppsala University, S-752 36 Uppsala, Sweden

* e-mail: Leonid.Dubrovinsky{at}geo.uu.se

We have heated magnesiowüstites (Mg0.5Fe0.5)O and (Mg0.8Fe0.2)O to temperatures of over 1000 K at pressures of over 80 GPa simulating the stability of the solid solution at physical conditions relevant to the Earth's lower mantle. The X-ray study of the externally heated samples in diamond-anvil cells shows that magnesiowüstite may dissociate into a magnesium-rich and an iron-rich oxide component. The result is important because the decomposition of magnesiowüstite into lighter and heavier phases will cause dynamic effects that could lead to mantle heterogeneity.

Key-words: magnesiowüstite, high pressure, immiscibility, Earth's lower mantle, diamond-anvil cell.




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Proc. Natl. Acad. Sci. USAHome page
J.-F. Lin, D. L. Heinz, H.-k. Mao, R. J. Hemley, J. M. Devine, J. Li, and G. Shen
Stability of magnesiowustite in Earth's lower mantle
PNAS, April 15, 2003; 100(8): 4405 - 4408.
[Abstract] [Full Text] [PDF]




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