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European Journal of Mineralogy; March, April 2003; v. 15; no. 2; p. 341-347; DOI: 10.1127/0935-1221/2003/0015-0341
© 2003 E. Schweizerbart'sche Verlagsbuchhandlung Science Publishers
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Articles

Synthesis and infrared spectroscopy of amphiboles along the tremolite-pargasite join

Giancarlo Della VENTURA1, Frank C. HAWTHORNE2, Jean-Louis ROBERT3 and Gianluca IEZZI3,*

1 Dipartimento di Scienze della Terra, Università della Calabria, I-87036 Arcavacata di Rende, Italy
2 Department of Geological Sciences, University of Manitoba, Winnipeg, Manitoba, Canada R3T 2N2
3 ISTO, UMR 6113, IA Rue de la Ferollerie, F-45071 Orléans Cedex 2, France

* Presently at: Dipartimento di Scienze della Terra, Università "G. D'Annunzio", I-66013 Chieti Scalo, Italy

Corresponding author, e-mail: dellaven{at}uniroma3.it

Amphiboles along the tremolite-pargasite join have been hydrothermally synthesized at 900°C, 3 kbar. Run products were characterized by optical and electron microscopy, powder X-ray diffraction and infrared spectroscopy. Under the experimental conditions used, there is complete solid-solution between tremolite and pargasite and the variation of cell parameters is linear as a function of composition. The infrared spectra in the principal OH-stretching region are consistent with the predictions of Hawthorne (1997) on local bond-valence grounds, and show strong short-range order of cations at the octahedral sites and strong coupling between Al at T(l) and Na at A.

Key-words: synthesis, tremolite-pargasite, cell-parameters, infrared spectra, short-range order..




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