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1 CREMINER-LA/ISR and Departamento de Geologia, Faculdade de Ciências da Universidade de Lisboa, Edifício C6-Piso 4, Campo Grande, 1749-016 Lisboa, Portugal
2 School of Ocean and Earth Sciences, Southampton Oceanographic Centre, Empress Dock, SO14 Southampton, United Kingdom
* Corresponding author, e-mail: isabelrc{at}fc.ul.pt
Serpentinized ultramafic rocks recovered during several recent oceanographic missions (1997–2002) on the Rainbow hydrothermal field and on the Saldanha seamount (36°14'N and 36°34'N, Mid-Atlantic Ridge) often exhibit late-stage carbonatization associated to secondary oxidation effects. These carbonate occurrences, mostly vein-filling aragonite, occasionally form dense webs almost completely engulfing and replacing the serpentinite itself.
The 87Sr/86Sr (approx. 0.709) and stable isotope signatures (
13CPDB = 0.2–3.3
;
18OV–SMOW = 32.2–35.2
) of the carbonate fraction in these serpentinites indicate carbonate precipitation from unmodified seawater, under abiotic conditions, and very low temperatures, close to bottom-water temperatures measured at the sampling stations. These analytical data imply that, unlike the serpentinite-hosted carbonate chimneys in the Lost City hydrothermal field (Ludwig et al., 2006), the vein-filling aragonite in the Rainbow and Saldanha serpentinites has a non-hydrothermal, low-temperature seawater origin.
Key-words: low-T carbonates, aragonite, serpentinites, Mid-Atlantic Ridge.
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